217 research outputs found
Low-energy electron-induced decomposition of 5-trifluoromethanesulfonyl-uracil: A potential radiosensitizer
Grant Nos. PD/BD/114447/2016 and PD/BD/114452/2016.
researcher position No. IF-FCT IF/00380/2014.
Doctoral Training Programme (RaBBiT, PD/00193/2012).
S.D. acknowledges support from FWF (P30332).
Polish National Science Center (NCN) under the Grant No. UMO-2014/14/A/ST4/00405 (J. R.).5-trifluoromethanesulfonyl-uracil (OTfU), a recently proposed radiosensitizer, is decomposed in the gas-phase by attachment of low-energy electrons. OTfU is a derivative of uracil with a triflate (OTf) group at the C5-position, which substantially increases its ability to undergo effective electron-induced dissociation. We report a rich assortment of fragments formed upon dissociative electron attachment (DEA), mostly by simple bond cleavages (e.g., dehydrogenation or formation of OTf-). The most favorable DEA channel corresponds to the formation of the triflate anion alongside with the reactive uracil-5-yl radical through the cleavage of the O-C5 bond, particularly at about 0 eV. Unlike for halouracils, the parent anion was not detected in our experiments. The experimental findings are accounted by a comprehensive theoretical study carried out at the M06-2X/aug-cc-pVTZ level. The latter comprises the thermodynamic thresholds for the formation of the observed anions calculated under the experimental conditions (383.15 K and 3 × 10-11 atm). The energy-resolved ion yield of the dehydrogenated parent anion, (OTfU-H)-, is discussed in terms of vibrational Feshbach resonances arising from the coupling between the dipole bound state and vibrational levels of the transient negative ion. We also report the mass spectrum of the cations obtained through ionization of OTfU by electrons with a kinetic energy of 70 eV. The current study endorses OTfU as a potential radiosensitizer agent with possible applications in radio-chemotherapy.publishersversionpublishe
Absolute frequency measurement of the magnesium intercombination transition
We report on a frequency measurement of the clock
transition of Mg on a thermal atomic beam. The intercombination
transition has been referenced to a portable primary Cs frequency standard with
the help of a femtosecond fiber laser frequency comb. The achieved uncertainty
is which corresponds to an increase in accuracy of six
orders of magnitude compared to previous results. The measured frequency value
permits the calculation of several other optical transitions from to
the -level system for Mg, Mg and Mg. We describe in
detail the components of our optical frequency standard like the stabilized
spectroscopy laser, the atomic beam apparatus used for Ramsey-Bord\'e
interferometry and the frequency comb generator and discuss the uncertainty
contributions to our measurement including the first and second order Doppler
effect. An upper limit of in one second for the short term
instability of our optical frequency standard was determined by comparison with
a GPS disciplined quartz oscillator.Comment: 8 pages, 8 figure
The HERMES Back Drift Chambers
The tracking system of the HERMES spectrometer behind the bending magnet
consists of two pairs of large planar 6-plane drift chambers. The design and
performance of these chambers is described. This description comprises details
on the mechanical and electronical design, information about the gas mixture
used and its properties, results on alignment, calibration, resolution, and
efficiencies, and a discussion of the experience gained through the first three
years of operation.Comment: 21 pages, LaTex, 16 figures include
How to measure the parity of the in collisions
Triggered by a recent paper by Thomas, Hicks and Hosaka, we investigate which
observables can be used to determine the parity of the from the
reaction near its production threshold. In
particular, we show that the sign of the spin correlation coefficient
for small excess energies yields the negative of the parity of the .
The argument relies solely on the Pauli principle and parity conservation and
is therefore model--independent.Comment: References completed, discussion on possible influence of background
added; conclusions unchange
Pseudovector vs. pseudoscalar coupling in one-boson exchange NN potentials
We examine the effects of pseudoscalar and pseudovector coupling of the pi
and eta mesons in one-boson exchange models of the NN interaction using two
approaches: time-ordered perturbation theory unitarized with the relativistic
Lippmann-Schwinger equation, and a reduced Bethe-Salpeter equation approach
using the Thompson equation. Contact terms in the one-boson exchange amplitudes
in time-ordered perturbation theory lead naturally to the introduction of
s-channel nucleonic cutoffs for the interaction, which strongly suppresses the
far off-shell behavior of the amplitudes in both approaches. Differences
between the resulting NN predictions of the various models are found to be
small, and particularly so when coupling constants of the other mesons are
readjusted within reasonable limits.Comment: 24 pages, 4 figure
Chiral perturbation theory
The main elements and methods of chiral perturbation theory, the effective
field theory of the Standard Model below the scale of spontaneous chiral
symmetry breaking, are summarized. Applications to the interactions of mesons
and baryons at low energies are reviewed, with special emphasis on developments
of the last three years. Among the topics covered are the strong,
electromagnetic and semileptonic weak interactions of mesons at and beyond
next--to--leading order in the chiral expansion, nonleptonic weak interactions
of mesons, virtual photon corrections and the meson--baryon system. The
discussion is limited to processes at zero temperature, for infinite volume and
with at most one baryon.Comment: 84 pages, Latex, 11 PostScript figures (in separate file) embedded
with epsfig.sty, complete ps file (compressed, uuencoded, 0.6 MB) available
via email on request; to appear in Progr. Part. Nucl. Phys., vol. 3
The three- and four-nucleon systems from chiral effective field theory
Recently developed chiral nucleon-nucleon (NN) forces at next-to-leading
order (NLO) that describe NN phase shifts up to about 100 MeV fairly well have
been applied to 3N and 4N systems. Faddeev-Yakubovsky equations have been
solved rigorously. The chiral NLO forces depend on a momentum cut-off \Lambda
lying between 540-600 MeV/c. The resulting 3N and 4N binding energies are in
the same range as found using standard NN potentials. In additon, low-energy 3N
scattering observables are very well reproduced like for standard NN forces.
Surprisingly, the long standing A_y-puzzle is resolved at NLO. The cut-off
dependence of the scattering observables is rather mild.Comment: 4 pp, revtex, 3 figure
Effective field theory and the quark model
We analyze the connections between the quark model (QM) and the description
of hadrons in the low-momentum limit of heavy-baryon effective field theory in
QCD. By using a three-flavor-index representation for the effective baryon
fields, we show that the ``nonrelativistic'' constituent QM for baryon masses
and moments is completely equivalent through O(m_s) to a parametrization of the
relativistic field theory in a general spin--flavor basis. The flavor and spin
variables can be identified with those of effective valence quarks. Conversely,
the spin-flavor description clarifies the structure and dynamical
interpretation of the chiral expansion in effective field theory, and provides
a direct connection between the field theory and the semirelativistic models
for hadrons used in successful dynamical calculations. This allows dynamical
information to be incorporated directly into the chiral expansion. We find, for
example, that the striking success of the additive QM for baryon magnetic
moments is a consequence of the relative smallness of the non-additive
spin-dependent corrections.Comment: 25 pages, revtex, no figure
Primakoff effect in eta-photoproduction off protons
We analyse data on forward eta-meson photoproduction off a proton target and
extract the eta to gamma gamma decay width utilizing the Primakoff effect. The
hadronic amplitude that enters into our analysis is strongly constrained
because it is fixed from a global fit to available gamma p to p eta data for
differential cross sections and polarizations. We compare our results with
present information on the two-photon eta-decay from the literature. We provide
predictions for future PrimEx experiments at Jefferson Laboratory in order to
motivate further studies.Comment: 5 pages, 6 figures, gamma-gamma*-eta form factor included, version to
appear in Eur. Phys. J. A
Simulation of thermal conductivity and heat transport in solids
Using molecular dynamics (MD) with classical interaction potentials we
present calculations of thermal conductivity and heat transport in crystals and
glasses. Inducing shock waves and heat pulses into the systems we study the
spreading of energy and temperature over the configurations. Phonon decay is
investigated by exciting single modes in the structures and monitoring the time
evolution of the amplitude using MD in a microcanonical ensemble. As examples,
crystalline and amorphous modifications of Selenium and are
considered.Comment: Revtex, 8 pages, 11 postscript figures, accepted for publication in
PR
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